Surface grafting of electrochemically crosslinked poly(3,4-ethylenedioxythiophene) (PEDOT) brushes via surface-initiated ring-opening metathesis polymerization

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dc.contributor.authorYavuz, Mustafa S.
dc.contributor.authorSotzing, Gregory A.
dc.date.accessioned2020-03-26T18:31:26Z
dc.date.available2020-03-26T18:31:26Z
dc.date.issued2012
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractHerein we demonstrated the preparation of 3,4-ethylenedioxythiophene (EDOT) containing polynorbornylene brushes on Au surfaces via surface-initiated ring-opening metathesis polymerization (SI-ROMP). Using solid-state oxidative crosslinking technique, these polymer brushes were electrochemically converted to conjugated polymer networks. Grazing-angle FTIR spectra of polymer brushes clearly showed the characteristic vibrations of EDOT and norbornylene groups. Furthermore, densely covered Au substrates with polynorbornylene brushes were characterized by using scanning electron microscopy and atomic force microscopy. (C) 2012 Elsevier Ltd. All rights reserved.en_US
dc.description.sponsorshipPHS from NIEHS/NIH [ES013557]en_US
dc.description.sponsorshipThe authors are grateful to Drs. Minhua Zhao and Bryan D. Huey for atomic force microscopy studies. This work was supported by PHS Grant ES013557 from NIEHS/NIH.en_US
dc.identifier.doi10.1016/j.eurpolymj.2012.01.013en_US
dc.identifier.endpage880en_US
dc.identifier.issn0014-3057en_US
dc.identifier.issue4en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage875en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.eurpolymj.2012.01.013
dc.identifier.urihttps://hdl.handle.net/20.500.12395/28441
dc.identifier.volume48en_US
dc.identifier.wosWOS:000302846700024en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPERGAMON-ELSEVIER SCIENCE LTDen_US
dc.relation.ispartofEUROPEAN POLYMER JOURNALen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subject3,4-Ethylenedioxythiophene (EDOT)en_US
dc.subjectPolynorbornylene brushen_US
dc.subjectGold surfaceen_US
dc.subjectConjugated polymeren_US
dc.subjectSurface-initiated ring opening metathesis polymerization (SI-ROMP)en_US
dc.titleSurface grafting of electrochemically crosslinked poly(3,4-ethylenedioxythiophene) (PEDOT) brushes via surface-initiated ring-opening metathesis polymerizationen_US
dc.typeArticleen_US

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