Synthesis and Binding Properties of Polymeric Calix[4]Arene Nitriles

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dc.contributor.authorUysal, Gülderen
dc.contributor.authorMemon, Shahabuddin
dc.contributor.authorYılmaz, Mustafa
dc.date.accessioned2020-03-26T16:37:26Z
dc.date.available2020-03-26T16:37:26Z
dc.date.issued2001
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractTwo new polymers containing pendant calix[4]arene units with nitrile functionalities at their lower rim have been synthesized via radical initiated reactions involving a vinylic monomer 6 {15,11,17,23-tetra-tert-butyl-25,26,27-tri-s(cyanomethoxy)-28-(2-acryloyloxy) ethoxycalix[4]arene} and with styrene. A five atom spacer group was incorporated between the bulky calixarene core and the acrylate moiety in border to minimize steric interactions which proved to impede the polymerization. The complexation studies were made by using liquid-liquid extraction procedures. It has been deduced from the observations that both polymers show a good selectivity towards Hg2+ like their precursor 5,11,17,23-tetra-tert-butyl-25,26,27-tricyanomethoxy-28-(2-hydroxy)ethoxycalix[4]arene 5, which supports their utility as adsorbents or potential candidate materials for fabricating membranes and sensors, which can separate or detect Hg2+ metal ions in a high selectivity.en_US
dc.identifier.citationYılmaz, M., Uysal, G., Memon, S., (2001). Synthesis and Binding Properties of Polymeric Calix[4]Arene Nitriles. Reactive & Functional Polymers, 50(1), 77-84.
dc.identifier.endpage84en_US
dc.identifier.issn1381-5148en_US
dc.identifier.issue1en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage77en_US
dc.identifier.urihttps://hdl.handle.net/20.500.12395/17619
dc.identifier.volume50en_US
dc.identifier.wosWOS:000172226500009en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherELSEVIER SCIENCE BVen_US
dc.relation.ispartofReactive & Functional Polymersen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectcalix[4]crownen_US
dc.subjectpendanten_US
dc.subjectco-polymeren_US
dc.subjectmetal ionsen_US
dc.subjectextractionen_US
dc.titleSynthesis and Binding Properties of Polymeric Calix[4]Arene Nitrilesen_US
dc.typeArticleen_US

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