THERMODYNAMIC STABILITIES - THERMODYNAMIC PARAMETERS OF SOME COMPLEXES OF 4'-MORPHOLINOACETOPHENONE 4-PHENYL-3-THIOSEMICARBAZONE

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dc.contributor.authorATALAY, T
dc.contributor.authorOZKAN, E
dc.date.accessioned2020-03-26T16:24:24Z
dc.date.available2020-03-26T16:24:24Z
dc.date.issued1994
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractThe stability constants (ln K) of the Co(II), Ni(II), Cu(II), Ag(I), Cd(II) and Hg(II) complexes with 4'-morpholinoacetophenone 4-phenyl-3-thiosemicarbazone were determined using a spectrophotometric method at different temperatures (25, 30, 35 and 40 +/- 0.1 degrees C) and at different ionic strengths (0.05, 0.10 and 0.20 mol dm(-3)) in 60% (v/v) aqueous dimethylformamide. Plots of thermodynamic stability constants at zero ionic strength (ln K-0) versus T-1 gave linear curves, and Delta H theta and Delta S theta were also calculated from these plots. Moreover, the changes in free energy for each metal-ligand system were calculated from the equation Delta G theta = -RT ln K-0.en_US
dc.identifier.doi10.1016/0040-6031(94)85105-0en_US
dc.identifier.endpage197en_US
dc.identifier.issn0040-6031en_US
dc.identifier.issue1en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage193en_US
dc.identifier.urihttps://dx.doi.org/10.1016/0040-6031(94)85105-0
dc.identifier.urihttps://hdl.handle.net/20.500.12395/16222
dc.identifier.volume246en_US
dc.identifier.wosWOS:A1994PR82000021en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherELSEVIER SCIENCE BVen_US
dc.relation.ispartofTHERMOCHIMICA ACTAen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectSTABILITYen_US
dc.subjectTHERMODYNAMICSen_US
dc.subjectTHIOSEMICARBAZONEen_US
dc.titleTHERMODYNAMIC STABILITIES - THERMODYNAMIC PARAMETERS OF SOME COMPLEXES OF 4'-MORPHOLINOACETOPHENONE 4-PHENYL-3-THIOSEMICARBAZONEen_US
dc.typeArticleen_US

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