Kinetics of the copolymerization of alkylene oxides with glycidyl methacrylate

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dc.contributor.authorAhmetli, Gulnare
dc.contributor.authorKocak, Ahmet
dc.contributor.authorYazicigil, Zafer
dc.date.accessioned2020-03-26T17:17:37Z
dc.date.available2020-03-26T17:17:37Z
dc.date.issued2007
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractIn the present study, the kinetics of copolymerization reaction of propylene oxide (PO) and butylene oxide (BO) with glycidyl methacrylate (GNLA.) in the presence of BF3 center dot O(C2H5)(2) catalyst were investigated. The kinetic parameters and activation energy of the copolymerization reaction were calculated. The amounts of reacting PO, BO, and GMA during copolymerization were determined by chromatographic method, because the same copolymerization conditions were carried out for them. It was determined that the copolymerization rate of PO (r(0)) and BO (r(0)) was higher than that of GMA, but activation energy (E) of GMA was higher than that of PO and BO. The rate of reaction, the rate constant, and activation energy were calculated from the amount of copolymer obtained with respect to time. The structures of synthesized copolymers were determined by the spectral and chemical analysis methods.en_US
dc.identifier.doi10.1002/app.27069en_US
dc.identifier.endpage3715en_US
dc.identifier.issn0021-8995en_US
dc.identifier.issue6en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage3710en_US
dc.identifier.urihttps://dx.doi.org/10.1002/app.27069
dc.identifier.urihttps://hdl.handle.net/20.500.12395/21451
dc.identifier.volume106en_US
dc.identifier.wosWOS:000250607200020en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherJOHN WILEY & SONS INCen_US
dc.relation.ispartofJOURNAL OF APPLIED POLYMER SCIENCEen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectkinetics (polymer)en_US
dc.subjectcopolymerizationen_US
dc.subjectalkylene oxidesen_US
dc.subjectglycidyl methacrylateen_US
dc.titleKinetics of the copolymerization of alkylene oxides with glycidyl methacrylateen_US
dc.typeArticleen_US

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