Synthesis and binding properties of two polymeric thiacalix[4]arenes

Basit Öğe Kaydı
dc.contributor.authorTabakci, B
dc.contributor.authorBeduk, AD
dc.contributor.authorTabakci, M
dc.contributor.authorYilmaz, M
dc.date.accessioned2020-03-26T17:04:24Z
dc.date.available2020-03-26T17:04:24Z
dc.date.issued2006
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractTwo new polymeric thiacalix[4]arenes were synthesized by the reaction of 5,11,17,23-tetra-tert-butyl-25,27-bis[(4-aminobenzyloxy)-26,28-dihydroxy]thiacalix[4]-arene 3 with terephthaloyl dichloride and 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetrahydroxy-thiacalix[4]arene 1 with chloromethylated polystyrene (Merrifield's resin). Complexation studies were made by using liquid-liquid and solid-liquid extraction procedures. It was found that the soluble polymeric thiacalix[4]arene derived from terephthaloyl dichloride is better at removing alkali (Li+, Na+, K+, and Cs+) and heavy metal (Cu2+, Cd2+, Hg2+, Pb2+, Co2+ and Ni2+) cations than the precursor thiacalix[4]arenes. Both the soluble polymer and the cross-linked polymer derived from Merrifield's resin are more efficient at removing transition metals from solution than the precursor thiacalix[4]arene. (c) 2005 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.reactfunctpolym.2005.08.013en_US
dc.identifier.endpage386en_US
dc.identifier.issn1381-5148en_US
dc.identifier.issn1873-166Xen_US
dc.identifier.issue3en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage379en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.reactfunctpolym.2005.08.013
dc.identifier.urihttps://hdl.handle.net/20.500.12395/20693
dc.identifier.volume66en_US
dc.identifier.wosWOS:000236451300009en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherELSEVIER SCIENCE BVen_US
dc.relation.ispartofREACTIVE & FUNCTIONAL POLYMERSen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectpolymeren_US
dc.subjectthiacalix[4]areneen_US
dc.subjectmetal extractionen_US
dc.titleSynthesis and binding properties of two polymeric thiacalix[4]arenesen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu