Utilization of Catalytic Properties of the Encapsulated Lipase with Calix[4]arene-Adorned Sporopollenin

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dc.contributor.authorOzyilmaz, Elif
dc.contributor.authorSayin, Serkan
dc.date.accessioned2020-03-26T20:11:39Z
dc.date.available2020-03-26T20:11:39Z
dc.date.issued2018
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractThe dihydrazide calix[4]arene was immobilized onto sporopollenin in order to encapsulate Candida rugosa lipase (CRL) via sol-gel entrapment. The kinetic resolution of the new encapsulated lipase was investigated for enantioselective hydrolysis of racemic naproxen methyl ester and 2-phenoxypropionic acid methyl ester. The results demonstrated that the activity and enantioselectivity of the lipase were improved when the lipase was encapsulated in the presence of calix[4]arene-immobilized sporopollenin. The encapsulated lipase showed an excellent rate of enantioselectivity against the (R/S)-naproxen methyl and (R/S)-2-phenoxypropionic acid methyl esters, with E = 350 and 295, respectively, compared to the free enzyme.en_US
dc.description.sponsorshipResearch Foundation of Selcuk University (BAP)Selcuk Universityen_US
dc.description.sponsorshipWe would like to thank The Research Foundation of Selcuk University (BAP) for their financial support of this work.en_US
dc.identifier.doi10.1080/10406638.2016.1200638en_US
dc.identifier.endpage281en_US
dc.identifier.issn1040-6638en_US
dc.identifier.issn1563-5333en_US
dc.identifier.issue3en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage272en_US
dc.identifier.urihttps://dx.doi.org/10.1080/10406638.2016.1200638
dc.identifier.urihttps://hdl.handle.net/20.500.12395/37122
dc.identifier.volume38en_US
dc.identifier.wosWOS:000431597300008en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherTAYLOR & FRANCIS LTDen_US
dc.relation.ispartofPOLYCYCLIC AROMATIC COMPOUNDSen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectcalixareneen_US
dc.subjectenantioselectivityen_US
dc.subjectlipaseen_US
dc.subjectracemic pro-drugsen_US
dc.subjectsporopolleninen_US
dc.titleUtilization of Catalytic Properties of the Encapsulated Lipase with Calix[4]arene-Adorned Sporopolleninen_US
dc.typeArticleen_US

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