Cu (II) Chemosensor Based on a Fluorogenic Bodipy-Salophen Combination: Sensitivity and Selectivity Studies

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dc.contributor.authorKursunlu, Ahmed Nuri
dc.contributor.authorSahin, Emel
dc.contributor.authorGuler, Ersin
dc.date.accessioned2020-03-26T19:23:29Z
dc.date.available2020-03-26T19:23:29Z
dc.date.issued2016
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractA new fluorescent chemosensor (Bodipy-S) derived from Bodipy and Salophen was developed. After the characterization of all compounds, the behavior of the chemosensor Bodipy-S toward p, d and f block-metal ions was investigated by UV-vis and fluorescence spectroscopy. This chemosensor can selectively detect to Cu (II) in methanol-aqueous solution based on chelation enhanced fluorescence (CHEF) and it almost exhibit to a fluorescence quenching effect with 20-fold. The binding constant of the fluorophore was interpreted by using of the Stern-Volmer method and the complex stoichiometry was defined by using Job's plot. Moreover, the effect of pH was performed by the fluorescence intensities of Bodipy-S in presence of Cu(II) ions. The chemosensor can be successfully used to the detection of Cu(II) in most areas.en_US
dc.description.sponsorship114Z095en_US
dc.description.sponsorshipWe thanks to Tubitak (114Z095) for financial support of this work. The authors express their appreciation to Prof. Ross W. Boyle for helpful discussions.en_US
dc.identifier.doi10.1007/s10895-016-1893-1en_US
dc.identifier.endpage2004en_US
dc.identifier.issn1053-0509en_US
dc.identifier.issn1573-4994en_US
dc.identifier.issue6en_US
dc.identifier.pmid27476068en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage1997en_US
dc.identifier.urihttps://dx.doi.org/10.1007/s10895-016-1893-1
dc.identifier.urihttps://hdl.handle.net/20.500.12395/33408
dc.identifier.volume26en_US
dc.identifier.wosWOS:000387271800010en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherSPRINGER/PLENUM PUBLISHERSen_US
dc.relation.ispartofJOURNAL OF FLUORESCENCEen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectBodipyen_US
dc.subjectSalophenen_US
dc.subjectCu (II)en_US
dc.subjectFluorescent chemosensoren_US
dc.subjectAbsorptionen_US
dc.titleCu (II) Chemosensor Based on a Fluorogenic Bodipy-Salophen Combination: Sensitivity and Selectivity Studiesen_US
dc.typeArticleen_US

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