L-proline derivatives based on a calix[4]arene scaffold as chiral organocatalysts for the direct asymmetric aldol reaction in water

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dc.contributor.authorAktaş, Mehmet
dc.contributor.authorUyanık, Arzu
dc.contributor.authorEymur, Serkan
dc.contributor.authorYılmaz, Mustafa
dc.date.accessioned2020-03-26T19:24:59Z
dc.date.available2020-03-26T19:24:59Z
dc.date.issued2016
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractA new series of water-compatible proline catalysts (4-6) derived from calixarene bearing a hydrophobic nature have been synthesised. It was found that the compound 4 was a highly efficient organocatalyst for aldol reactions occurred in the water. Under optimised reaction conditions, high yields (up to 82%), good enantioselectivities (ee up to 81%) and high diastereoselectivities (dr up to 91:9) were obtained.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey [TUBITAK]Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [112T349]; Scientific and Technological Research Council of Turkey [TUBITAK CMST COST Action]Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [CM1005]; Research Foundation of Selcuk University (BAP)Selcuk Universityen_US
dc.description.sponsorshipThis work supported by Scientific and Technological Research Council of Turkey [TUBITAK grant number 112T349 and CMST COST Action CM1005], and the Research Foundation of Selcuk University (BAP).en_US
dc.identifier.doi10.1080/10610278.2015.1073288en_US
dc.identifier.endpage359en_US
dc.identifier.issn1061-0278en_US
dc.identifier.issn1029-0478en_US
dc.identifier.issue05.06.2020en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage351en_US
dc.identifier.urihttps://dx.doi.org/10.1080/10610278.2015.1073288
dc.identifier.urihttps://hdl.handle.net/20.500.12395/33763
dc.identifier.volume28en_US
dc.identifier.wosWOS:000373283800004en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherTAYLOR & FRANCIS LTDen_US
dc.relation.ispartofSUPRAMOLECULAR CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectCalix[4]areneen_US
dc.subjectorganocatalysisen_US
dc.subjectenantioselectiveen_US
dc.subjectaldolen_US
dc.titleL-proline derivatives based on a calix[4]arene scaffold as chiral organocatalysts for the direct asymmetric aldol reaction in wateren_US
dc.typeArticleen_US

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