Tripodal Schiff Bazli Ligandin Sentezi ve Üç Merkezli Geçiş Metal Komplekslerinin incelenmesi

Bu çalmadali maddesi olarak siyanür klorür kulanid Siyanür klorür, sodyum karbonat ve benzenli ortamda 4-hidroksibenzaldehitlereaksiyona girerek 2,4,6-trip-formienok) 13,5-triazin (TRIPOD) elde edildi. Daha sonra, Tripedal Schiff bazi literature gore TRIPOD le aminin, kenetleme reaksiyonu le sentezlendi Tripedal Schiff bezinin sentezi için, 2-aminomet piridin kullanildi. Etanola ortamda pozulmde 2,4,6-tris(2-piridimino 4-formienoksi)-1,3,5-triazin ligandina etanolde çözülmüş olan Nil) Coll) ve Cuci) a tat tuzlari ilave edilerek renkli kompleksler elde edildi. Sonu olarak, tripodal Schiff baz igandi ve kompleksleri izoSchiff bazle edildi ve elementel anal, FT-R, H NMR ve manyetik susseptiblite ile yapıları aydinlatildi

In this study, cyanuric chloride was used as a starting mate 245Trisp-formyphenoxy-1,35 traine (TRIPOD) was obtained from the reaction of cyanuric chloride with p-hydroxybenzeye in the presence of sodium carbonate and benzene. Then Tripodal Schi's base was synthesized by the coupling reaction of TRIPOD with amine according to the literature. The amine used in the synthesis of tripode schits bases 2-aminomethyridine. The colored complexes were obtained by the addition of acetate salts of NKI), Co(II) and Cu(I) in ethanol to the solution of 2,4,6-tri2-pyridilimino 4-formylphenoxyl-1,3,5-triazine dissolved in ethanol. In conclusion, tripodal Schilf bases ligand and their complexes were isolated and their structures were characterized by FT-IR and H NMR spectra, elemental analysis and magnetic susceptibility