Synthesis of N-(4 '-benzo[15-crown-5])thiophenoxyphenylaminoglyoxime and its complexes with some transition metals

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dc.contributor.authorCoskun, Ahmet
dc.contributor.authorKarapinar, Emin
dc.date.accessioned2020-03-26T17:27:55Z
dc.date.available2020-03-26T17:27:55Z
dc.date.issued2008
dc.departmentSelçuk Üniversitesien_US
dc.description.abstract4-(Chloroacetyl)diphenyl thioether (1) was synthesized from chloroacetyl chloride and diphenyl thioether in the presence of AlCl3 as catalyst in a Friedel-Crafts reaction. Subsequently, its keto oxime (2) and glyoxime (3) derivatives were prepared. N-(4'-Benzo[15-crown-5]thiophenoxyphenylaminoglyoxime (H2L) and its sodium chloride complex (H2L center dot NaCl) were prepared from 4-(thiophenoxy)chlorophenylglyoxime (3), 4'-aminobenzo[15-crown-5] and sodium bicarbonate or sodium bicarbonate and sodium chloride. Ni(II), Co(II) and Cu(II) complexes of H2L and H2L center dot NaCl have a metal-ligand ratio of 1:2 and the ligand coordinates through the two N atoms, as do most of the vic-dioximes. The BF2-capped Ni(II) mononuclear complex of the vic-dioxime was prepared. The macrocyclic ligands and their transition metal complexes were characterized on the basis of FT-IR, H-1 NMR, C-13 NMR spectroscopy and elemental analyses data.en_US
dc.identifier.doi10.1007/s10847-007-9352-xen_US
dc.identifier.endpage64en_US
dc.identifier.issn1388-3127en_US
dc.identifier.issn1573-1111en_US
dc.identifier.issue01.02.2020en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage59en_US
dc.identifier.urihttps://dx.doi.org/10.1007/s10847-007-9352-x
dc.identifier.urihttps://hdl.handle.net/20.500.12395/22674
dc.identifier.volume60en_US
dc.identifier.wosWOS:000252475000008en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSPRINGERen_US
dc.relation.ispartofJOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectBF2+-capped complexen_US
dc.subjectcrown compoundsen_US
dc.subjectglyoximesen_US
dc.subjecttransition metal complexesen_US
dc.titleSynthesis of N-(4 '-benzo[15-crown-5])thiophenoxyphenylaminoglyoxime and its complexes with some transition metalsen_US
dc.typeArticleen_US

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