Thermal Degradation Behaviour of Ni(II) Complex of 3,4-Methylenedioxaphenylaminoglyoxime

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dc.contributor.authorKarapinar, Emin
dc.contributor.authorGubbuk, Ilkay Hilal
dc.contributor.authorTaner, Bilge
dc.contributor.authorDeveci, Pervin
dc.contributor.authorOzcan, Emine
dc.date.accessioned2020-03-26T18:44:13Z
dc.date.available2020-03-26T18:44:13Z
dc.date.issued2013
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractThermal degradation behaviour of the Ni(II) complex of 3,4-methylenedioxaphenylaminoglyoxime was investigated by TG, DTA, and DTG at a heating rate of 10 degrees C min(-1) under dinitrogen. The acquired experimental data shows that the complex is thermally stable up to 541 K. The pyrolytic decomposition process occurs by melting metal complex and metal oxide remains as final product. The energies of the reactions involved and the mechanism of decomposition at each stage have been examined. The values of kinetic parameters such as activation energy (E), preexponential factor (A) and thermodynamic parameters such as enthalpy (Delta H), entropy (Delta S), and Gibbs free energy (Delta G) are also evaluated.en_US
dc.description.sponsorshipScientific and Technical Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [108T655]; Selcuk University Research FoundationSelcuk University [SUBAP 08101031]en_US
dc.description.sponsorshipThe authors thank the Scientific and Technical Research Council of Turkey (TUBITAK, Grant no. 108T655) and Selcuk University Research Foundation (SUBAP 08101031) for the financial support of this work.en_US
dc.identifier.doi10.1155/2013/548067en_US
dc.identifier.issn2090-9063en_US
dc.identifier.issn2090-9071en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://dx.doi.org/10.1155/2013/548067
dc.identifier.urihttps://hdl.handle.net/20.500.12395/29961
dc.identifier.wosWOS:000326839600001en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherHINDAWI PUBLISHING CORPORATIONen_US
dc.relation.ispartofJOURNAL OF CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.selcuk20240510_oaigen_US
dc.titleThermal Degradation Behaviour of Ni(II) Complex of 3,4-Methylenedioxaphenylaminoglyoximeen_US
dc.typeArticleen_US

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