Synthesis and characterization of 4-(alkylaminoisonitrosoacetyl) diphenyl ether and some of their metal complexes

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dc.contributor.authorCoskun, Ahmet
dc.contributor.authorYilmaz, Funda
dc.date.accessioned2020-03-26T17:27:51Z
dc.date.available2020-03-26T17:27:51Z
dc.date.issued2008
dc.departmentSelçuk Üniversitesien_US
dc.description.abstract4-(Chloroacetyl) diphenyl ether ( I) was synthesized from chloroacetyl chloride and diphenyl ether in the presence of AlCl3 as catalyst in a Friedel-Crafts reaction. Subsequently, its keto oxime (II) derivative was prepared. Then 3 new substituted 4-(alkylaminoisonitrosoacetyl) diphenyl ether ligands derived from 4-(phenoxy) phenyloxylohydroxymoyl chloride and corresponding amines were synthesized. The following aromatic and aliphatic amines were used for the ligands ethanolamine, 2-amino-4- methylphenol, and 2(aminomethyl) pyridine. Mononuclear or binuclear Co(II), Ni(II), Cu(II), and Cd(II) complexes of the ligands were synthesized. The structures of these ligands were identified by FT-IR, H-1-NMR, and C-13-NMR spectral data and elemental analysis, and the structures of the complexes were identified by FT-IR, ICP-AES, elemental analysis, and magnetic susceptibility measurements.en_US
dc.identifier.endpage312en_US
dc.identifier.issn1300-0527en_US
dc.identifier.issue3en_US
dc.identifier.startpage305en_US
dc.identifier.urihttps://hdl.handle.net/20.500.12395/22661
dc.identifier.volume32en_US
dc.identifier.wosWOS:000257116100004en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakTR-Dizinen_US
dc.language.isoenen_US
dc.publisherSCIENTIFIC TECHNICAL RESEARCH COUNCIL TURKEY-TUBITAKen_US
dc.relation.ispartofTURKISH JOURNAL OF CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectketoximeen_US
dc.subjecttransition metal complexesen_US
dc.subjectbinuclear complexesen_US
dc.titleSynthesis and characterization of 4-(alkylaminoisonitrosoacetyl) diphenyl ether and some of their metal complexesen_US
dc.typeArticleen_US

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