Synthesis of a glutaraldehyde derivative of calix[4]arene as a cross-linker reagent for lipase immobilization

Basit Öğe Kaydı
dc.contributor.authorÖzcan, Fatih
dc.contributor.authorŞahin, Özlem
dc.contributor.authorYılmaz, Mustafa
dc.date.accessioned2020-03-26T17:40:21Z
dc.date.available2020-03-26T17:40:21Z
dc.date.issued2009
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractThis article describes the synthesis of a new calix[4]arene 1,3-distal glutaraldehyde derivative 4 as a cross-linker-reagent for immobilization of Candida rugosa lipase (CRL). p-tert-Butylcalix[4]arene 1,3-distal diaminoalkyl derivative (3) synthesized via aminolysis reaction of 5,11,17,23-tert-butyl-25,27-ethoxycarbonylmethoxy-26,28-hydroxycalix[4]arene (2) with 1,8-diaminooctane. Compound 3 was converted to its aldehyde derivative (4) by the treatment with glutaraldehyde solution. 4 was used in lipase immobilization in order to see the role of calix[4]arene binding site on the lipase activity and stability. It was observed that the immobilized lipase activity was maintained at levels exceeding 95% of its original activity after 40 min.en_US
dc.identifier.doi10.1007/s10847-008-9496-3en_US
dc.identifier.endpage129en_US
dc.identifier.issn1388-3127en_US
dc.identifier.issn1573-1111en_US
dc.identifier.issue01.02.2020en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage123en_US
dc.identifier.urihttps://dx.doi.org/10.1007/s10847-008-9496-3
dc.identifier.urihttps://hdl.handle.net/20.500.12395/23889
dc.identifier.volume63en_US
dc.identifier.wosWOS:000262651300015en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSPRINGERen_US
dc.relation.ispartofJOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectCalixareneen_US
dc.subjectCross linkeren_US
dc.subjectImmobilizationen_US
dc.subjectCandida rugosa lipaseen_US
dc.subjectGlutaraldehydeen_US
dc.titleSynthesis of a glutaraldehyde derivative of calix[4]arene as a cross-linker reagent for lipase immobilizationen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu