Synthesis and Oxoanions (Dichromate/Arsenate) Sorption Study of N-methylglucamine Derivative of Calix[4]arene Immobilized Onto Poly[(Phenyl Glycidyl Ether)-co-formaldehyde]

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dc.contributor.authorSayın, Serkan
dc.contributor.authorÖzcan, Fatih
dc.contributor.authorMemon, Shahabuddin
dc.contributor.authorYılmaz, Mustafa
dc.date.accessioned2020-03-26T18:05:06Z
dc.date.available2020-03-26T18:05:06Z
dc.date.issued2010
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractThe article describes synthesis as well as the evaluation of sorption properties of new N-methylglucamine substituted calix[ 4] arene and its poly[(phenyl glycidyl ether)-co-formaldehyde] immobilized product. Firstly, 5,17-bis-[(N-methylglucamine)methyl]-25,26,27,28-tetra-hydroxy-calix[4]arene (3) was synthesized by the treatment of calix[4] arene with a secondary amine N-methylglucamine and formaldehyde via Mannich reaction. The immobilization of 3 onto poly[( phenyl glycidyl ether)-co-formaldehyde] to form calixarene based polymer (4) was carried out under suitable reaction conditions via nucleophilic substitution reaction. All the new compounds were characterized by a combination of FT-IR, H-1-NMR spectroscopic and elemental analysis techniques. The sorption studies of 4 reveal that it is an excellent material for the removal of toxic oxoanions especially arsenate from aqueous environment. To understand the selectivity of 4, we also examined the retention of dichromate anions in the presence of Cl-, NO3- and SO42- anions at pH 1.5.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [107T873]; Research Foundation of Selcuk University (BAP)Selcuk Universityen_US
dc.description.sponsorshipWe would like to thank The Scientific and Technological Research Council of Turkey (TUBITAK Grant No. 107T873) and The Research Foundation of Selcuk University (BAP) for financial support of this work.en_US
dc.identifier.citationSayın, S., Özcan, F., Yılmaz, M., Memon, S., (2010). Synthesis and Oxoanions (Dichromate/Arsenate) Sorption Study of N-methylglucamine Derivative of Calix[4]arene Immobilized Onto Poly[(Phenyl Glycidyl Ether)-co-formaldehyde]. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 67(2010), 385-391. Doi:10.1007/s10847-009-9720-9
dc.identifier.doi10.1007/s10847-009-9720-9en_US
dc.identifier.endpage391en_US
dc.identifier.issn1388-3127en_US
dc.identifier.issn1573-1111en_US
dc.identifier.issue03.04.2020en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage385en_US
dc.identifier.urihttps://dx.doi.org/10.1007/s10847-009-9720-9
dc.identifier.urihttps://hdl.handle.net/20.500.12395/25302
dc.identifier.volume67en_US
dc.identifier.wosWOS:000277958600017en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorSayın, Serkan
dc.institutionauthorÖzcan, Fatih
dc.institutionauthorYılmaz, Mustafa
dc.language.isoenen_US
dc.publisherSPRINGERen_US
dc.relation.ispartofJournal of Inclusion Phenomena and Macrocyclic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectCalix[4]areneen_US
dc.subjectDichromateen_US
dc.subjectArsenateen_US
dc.subjectSorptionen_US
dc.subjectProton-swicthableen_US
dc.titleSynthesis and Oxoanions (Dichromate/Arsenate) Sorption Study of N-methylglucamine Derivative of Calix[4]arene Immobilized Onto Poly[(Phenyl Glycidyl Ether)-co-formaldehyde]en_US
dc.typeArticleen_US

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